Chemteach

UC Home > Chemteach 

Chemteach University of Canterbury, Christchurch, New Zealand

Contact

Joan Gladwyn or

Rachel Wright

+64 3 364 2178

outreach

@canterbury.ac.nz

Book Review

Napoleon's Buttons: 17 Molecules that Changed History

Dr Penny Le Couteur and Jay Burreson

Reviewed by Suzanne Boniface, Queen Margaret College (now Victoria University Wellington).

The title of this book is deceptive unless one reads the sub-title – 17 molecules that changed history . The story about “Napoleon's Buttons” is recorded in the introduction. It illustrates how often there can be a ‘chemical reason' behind an event that changes the course of history. The tale is told of how Napoleon's troops were defeated in Russia because the tin used to make the buttons on their great-coats disintegrated in the low temperatures. This is a well used story among chemical educators the world over even though historical evidence indicates the story is more likely apocryphal than fact. Despite this it wonderfully illustrates how small changes in the underlying chemistry of substances can lead to changes in properties that have enormous consequences for individuals and ultimately, for society. In this book seventeen ‘molecules' (one could argue that salt is not a molecule) that had a huge influence on society and world events are explored. In each case the history of the discovery and use of the molecules is discussed along with their world shaping influence.

The chemical industry as we know it today had its origins in the development of synthetic dyes in the 19 th century. However, the influence of some particular molecules on world history goes back much further. This is apparent in the compounds chosen by the authors. These fall into two main groups; those from natural sources and those made in the laboratory. Valuable compounds from natural sources have been sought after in every age and have governed many aspects of history. For example desire for glucose (sugar) and cellulose (cotton) drove and sustained the slave trade to the Americas from the seventeenth century. The desire for spices, particularly pepper, pushed forward the ‘Age of Discovery' as new routes to India were sought to break the Venetian monopoly on the spice trade. Salt, silk and oleic acid (olive oil) are also noted for their influence on trade across the centuries. Vitamin C made a difference to the length of the journeys that sailors could undertake and so new worlds opened up.

The advance of the chemical industry in the past century and a half has given rise to compounds made in the laboratory or factory. Many, such as the dye, indigo and the vitamin, ascorbic acid are identical to those found in nature while others, like aspirin, have small variations to the natural product which gives them more useful properties. ‘Wonder drugs' such as antibiotics, steroids, contraceptives, anesthetics are explored as are the alkaloid molecules, caffeine, morphine and nicotine. Once again small changes on the molecules that have lead to new, sometimes useful and sometimes controversial compounds are explored from a historical and a chemical perspective. In each case the chosen chemicals have been responsible for a key event in history or for a series of events that have transformed society.

The authors weave the stories of each compound's discovery, use, and influence with discussions of chemical properties. They consistently make connections between chemical structures and historical episodes. Thus the book is not written in chronological order but chapters are based on connections between similar or related molecules. For example following on from the chapter on cellulose is one about nitro compounds and the link is the discovery of ‘gun cotton' and the story of Schonberg's exploding apron. To quote the authors ‘this book is not about the history of chemistry; rather it is about chemistry in history.'

The key to this book is the connection between chemical structures and the desirable properties of each compound. When helpful, chemical structures are included in the text and the significance of any changes to the structures clearly explained. For example the position of the –OH group in the hydrocarbon chain of the molecule produced by bees helps them distinguish between a worker and a queen. A brief explanation of ‘organic chemistry' and the structural representation of organic molecules are included in the introduction to the book. The authors cleverly minimise the complexity of some of the organic molecules by highlighting the important group under discussion and treating the rest of the molecule as something that this group hangs from.

here is much mention in current chemistry education literature of the need to make ‘real life' connections for our students. This book is a gold mine of anecdotes, stories and every-day examples that link to many aspects of the chemistry that we teach in schools and universities. As such it should be found in every school's science department resources and among the science books in school libraries. It is a great read for anyone with a basic understanding of chemistry and an interest in science and history. The authors have skillfully blended of history, chemistry and culture in a wonderfully readable, interesting book.

 
 
© University of Canterbury - Christchurch, New Zealand